Hastelloy G-30: The Phosphoric Acid-Resistant Superalloy Guide

Wet-process phosphoric acid — the acid used to make DAP, MAP, and TSP fertilizers — is one of the most corrosive environments in the chemical industry. Hastelloy G-30 (UNS N06030) was developed specifically for this service. This guide covers the chemistry, ASTM B575 specification, G-30 vs C276 comparison, and the practical service limits in 28–54% P₂O₅ wet-process acid with chlorides and fluorides.

Updated: June 2026  •  Reading time: 11 min  •  By: Phosphoric Acid & Fertilizer Team

Why Phosphoric Acid Eats Metal

Phosphoric acid is unique in its corrosivity because the industrial product is not the pure reagent-grade H₃PO₄ you can buy from a lab supplier. Wet-process phosphoric acid (WPA) — produced by digesting phosphate rock with sulfuric acid — contains a long list of contaminants that make it far more aggressive than pure H₃PO₄:

  • Free sulfuric acid (1–4% H₂SO₄): the digestion acid that was not fully consumed.
  • Fluorides (1–3% F⁻ as HF, H₂SiF₆, fluorosilicates): from the fluorapatite mineral in the rock.
  • Chlorides (0.1–1% Cl⁻): from the rock and from the sulfuric acid.
  • Suspended solids (gypsum, silica, undigested rock): 10–30% by weight: high-velocity erosion.
  • Aluminum, iron, magnesium, sodium, potassium, uranium: from the rock, present as dissolved ions.

The result is an acid that is hot (60–110°C), concentrated (28–54% P₂O₅), aerated, chloride- and fluoride-bearing, with high solids content. 316L stainless fails in months. 904L fails in 1–2 years. Alloy 20 lasts 5–10 years. Hastelloy G-30 typically delivers 15+ years of service life in the most aggressive positions in a DAP/MAP plant.

Hastelloy G-30: Designed for Wet-Process H₃PO₄

G-30 (UNS N06030) was developed by Haynes International in the 1980s specifically as an upgrade to G-3 (UNS N06985) for the phosphate fertilizer industry. The alloy is a Ni-Fe-Cr-Mo-Cu-W alloy with the right balance of Cr (for oxidizing-acid resistance), Mo (for reducing-acid resistance), and Cu (for sulfuric acid resistance) — without the tungsten content of C276 that makes welding more difficult.

G-30 Design Priorities

Optimize for: 30–55% H₃PO₄, 60–110°C, with 1–3% F⁻ and 0.1–1% Cl⁻, plus 1–4% residual H₂SO₄ and entrained solids.

Original Application

Phosphoric acid evaporators, agitator shafts, attack tank piping, filter underflow piping, and the 28% → 54% P₂O₅ concentration train.

Best Today

Replacement of Alloy 20 and C276 in WPA service. Welded construction with ERNiCrMo-11 or matching G-30 filler.

Chemical Composition (UNS N06030)

Element G-30 (N06030) Function
Nickel (Ni) 43.0 min (typically 50–55) Austenite stability, SCC resistance
Chromium (Cr) 28.0 – 31.5 Oxidizing acid resistance (key)
Iron (Fe) 13.0 – 17.0
Molybdenum (Mo) 4.0 – 6.0 Reducing acid + Cl⁻ resistance
Tungsten (W) 1.5 – 4.0 Additional pitting resistance
Copper (Cu) 1.0 – 2.4 H₂SO₄ resistance (key)
Niobium (Nb) 0.30 – 1.50 Carbide stabilization
Carbon (C) 0.03 max
Mn / Si / S / P ≤ 1.5 / ≤ 0.8 / ≤ 0.02 / ≤ 0.04 Residual limits
PREN (typical) ~45

Three features stand out: 30% Cr (very high — gives the alloy resistance to oxidizing conditions like concentrated HNO₃ and F⁻-rich acid), 2% Cu (resistance to H₂SO₄ in the digestion acid), and 5% Mo + 2.5% W (resistance to Cl⁻ and reducing acid).

ASTM B575 / B622 / B626 Product Forms

Product Form ASTM Specification Typical Sizes
Plate, sheet, strip B575 0.5 to 50 mm thick
Seamless pipe & tube B622 1/2″ to 12″ NPS
Welded pipe & tube B626, B619 1/2″ to 48″ NPS
Bar B581 (or B574 for round bar) 6 to 300 mm round
Forgings & fittings B462, B366 1/2″ to 24″ NPS, 150#–600#

ASME “SB” versions are required for Section VIII pressure-vessel service. Welding electrode per SFA-5.11 is ENiCrMo-11; per SFA-5.14 is ERNiCrMo-11. Both are available from Special Metals, Haynes, and select European mills.

G-30 vs C276: Head-to-Head

Property G-30 (N06030) C276 (N10276)
Ni content ~53% ~57%
Cr content 30% (high) 15.5% (lower)
Mo content 5% 16% (high)
W content 2.5% 3.5%
Cu content 2% (deliberate) < 0.5%
PREN ~45 ~45
Best at: Oxidizing acid, F⁻, H₂SO₄ + HNO₃ mix Reducing acid, hot HCl, severe Cl⁻
Weldability Good — better than C276 Good — but prone to HAZ cracking if contaminated
Cost (relative) 1.0× (baseline) 1.1–1.2×

Where G-30 wins

  • Wet-process phosphoric acid (any concentration, any temperature, with F⁻ + Cl⁻)
  • Concentrated HNO₃ + HF pickling (semiconductor, stainless)
  • Sulfuric + nitric mixed acid (metal finishing)
  • Phosphate fertilizer evaporator tubes

Where C276 wins

  • Hot concentrated HCl (any concentration above 10%)
  • Wet FGD scrubber with reducing-acid conditions
  • Severe chloride with no oxidizer
  • Any environment where the Cr is consumed and only Mo+W can save you

G-30 vs Alloy 20: When to Switch

Alloy 20 (UNS N08020) is the previous-generation WPA material. The upgrade rule of thumb:

Service Alloy 20 G-30
Filter acid (28% P₂O₅, 75°C, with F⁻ + gypsum) 1.0–1.5 mm/yr 0.1–0.3 mm/yr
Evaporator inlet (40% P₂O₅, 90°C) 1.5–2.5 mm/yr 0.2–0.5 mm/yr
Evaporator outlet (54% P₂O₅, 110°C) > 3 mm/yr (fail) 0.5–1.0 mm/yr (acceptable)
Product acid storage (54% P₂O₅, 50°C) 0.5–1.0 mm/yr < 0.2 mm/yr
The crossover point for G-30 over Alloy 20 is when the acid concentration exceeds 40% P₂O₅ and the temperature is above 80°C. Below that, Alloy 20 is the economical choice. Above that, G-30 pays for itself many times over — typically by avoiding one unplanned shutdown in 10 years.

G-30 vs G-35: The New Generation

Hastelloy G-35 (UNS N06035) is the latest-generation upgrade to G-30, with even higher Cr (33%) and lower Fe (≤ 2%) to handle the new “cleaner acid” WPA chemistries used in high-purity phosphate applications (lithium-iron-phosphate batteries, food-grade phosphates).

Property G-30 G-35
Cr 30% 33%
Mo 5% 8%
Fe 15% ≤ 2%
WPA service life (years) 10–15 15–25
Best for Standard WPA, evaporator High-purity, hot concentrated WPA, FGD + Cl⁻
Indicative price (USD/kg) ~$40 ~$55

For new DAP/MAP plant construction, G-35 is the modern standard. For repair and replacement of existing G-30 equipment, G-30 remains cost-effective and readily available.

Corrosion Data in Wet-Process Acid

Acid Composition Temperature Alloy 20 C276 G-30 G-35
28% P₂O₅, 2% H₂SO₄, 1% F⁻ 75°C 0.8 mm/y 0.3 mm/y 0.15 mm/y 0.10 mm/y
40% P₂O₅, 1% H₂SO₄, 0.5% F⁻ 90°C 2.0 mm/y 0.5 mm/y 0.25 mm/y 0.15 mm/y
54% P₂O₅, 0.5% H₂SO₄, 0.2% F⁻ 110°C 3.5 mm/y (fail) 0.7 mm/y 0.4 mm/y 0.25 mm/y
30% P₂O₅ + 5% HNO₃, 50°C 1.5 mm/y 2.0 mm/y (C276 is reduced in oxidizing) 0.3 mm/y 0.2 mm/y

Applications in Phosphate Fertilizer Plants

Attack Tank Agitators & Shafts

Mixing phosphate rock with sulfuric acid. The most aggressive position in the plant — 80°C, 30% solids, fluoride + chloride. G-30 last 10+ years vs Alloy 20’s 2–3 years.

Filter Acid Piping

From the horizontal belt filter to the evaporator. 28% P₂O₅ at 70°C with gypsum slurry. G-30 is the global standard; some plants use rubber-lined carbon steel as a lower-cost alternative.

Evaporator Tube Bundles

Multiple-effect evaporator concentrating 28% → 54% P₂O₅. Tubes see increasing temperature and acid concentration as they climb the effects. G-30 tube life: 12–18 years.

Clarifier & Thickener Internals

Rakes, drive shafts, feed wells. G-30 castings (CW-2M equivalent) are available for thickener drive mechanisms.

Product Acid Storage Tanks

54% P₂O₅ merchant-grade acid at ambient. G-30 or rubber-lined CS; Alloy 20 is marginal at this concentration.

DAP / MAP Reactor Internals

Phosphoric acid + ammonia reaction. Corrosive slurry at 80–100°C. G-30 reactor internals; in some positions, glass-lined CS is used.

Specify G-30 to ASTM B575 / B622 with supplementary S4 (PMI 100%) and S6 (corrosion test per ASTM G28A). We can supply plate, sheet, bar, seamless tube, welded pipe, and welding consumables from stock, EN 10204 3.1 or 3.2. Request a quote or chat on WhatsApp 15793002733.

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Detailed Corrosion Rates: G-30 in the Full WPA Process Stream

The wet-process phosphoric acid (WPA) plant contains multiple unit operations, each with its own corrosive fingerprint. A single alloy rarely covers the entire plant — G-30 is specified for the most aggressive sections and a less expensive alloy (Alloy 20, 904L, or 316L) for the rest:

Plant Location Corrosive Species T (°C) G-30 Rate (mm/y) C276 Rate (mm/y) Recommendation
Phosphate rock slurry piping H₃PO₄ + H₂SO₄ + solid rock fines (abrasive) 40–60 < 0.05 < 0.05 Both OK; Alloy 20 cheaper choice
Reaction (attack) tank — vapor space HF + SiF₄ vapor; no liquid contact 75–85 0.02 < 0.02 G-30 preferred (cheaper than C276)
Reaction tank — submerged 30% P₂O₅ + 3% H₂SO₄ + 1.5% F⁻ + 1% Cl⁻ + gypsum solids 75–85 0.08 0.05 G-30 sufficient; C276 overkill
Filter acid — filtrate side 28% P₂O₅ + 2% H₂SO₄ + 0.5% F⁻ + 0.5% Cl⁻ 60–70 0.05 < 0.05 Alloy 20 for piping; G-30 for critical areas
Filter acid — under gypsum cake (crevice) Same as above + stagnant conditions 60–70 0.15 0.08 G-30 minimum; crevice risk is real
Evaporator — first effect tubes (forced circulation) 40% P₂O₅ at ~105°C + F⁻ + Cl⁻ + gypsum scale 105–115 0.25 0.12 G-30 or C276 mandatory. Alloy 20 fails above 80°C here
Evaporator — second effect (lower T) 45% P₂O₅ at ~85°C 85 0.12 0.06 G-30 acceptable; C276 preferred for long life
Concentrated acid storage tank (54% P₂O₅) 54% P₂O₅ + residual F⁻ + Cl⁻; stagnant 40–50 0.03 0.02 316L + rubber lining is standard. G-30 / C276 for unlined option
Fluosilicic acid recovery condenser 18–22% H₂SiF₆ (from scrubber water) + 1% H₂SO₄ 50–70 0.06 < 0.05 G-30 best balance of cost/resistance

Fabrication of Hastelloy G-30: Welding, Forming & Machining Guide

G-30 is a fully austenitic solid-solution alloy, which makes it fundamentally easier to weld than precipitation-hardenable or duplex grades — but it has its own specific requirements:

Welding

  • Processes: GTAW (TIG) preferred for root passes and thin sections; GMAW (MIG) for fill passes on thick sections; SMAW (stick) for field repair — all standard.
  • Filler metal: ERNiCrMo-11 (AWS A5.14) for TIG — this is the matching filler. ERNiCrMo-3 (Inconel 625 filler) is an acceptable alternative for dissimilar-metal welds to carbon steel or 316L but NOT for matching G-30-to-G-30 welds in corrosive service (the lower Mo and absence of W in 625 filler will make the weld metal the weak link).
  • Shielding gas: 100% argon for GTAW; 75%Ar/25%He or 100% Ar for GMAW. No hydrogen additions — hydrogen in the shielding gas increases the risk of hot-cracking in high-Ni alloys.
  • Preheat: Not required. Interpass temperature: ≤ 150°C. Lower is better — 100°C max for thin sections.
  • Post-weld heat treatment: Not required. G-30 is solid-solution strengthened and the as-welded condition meets all ASTM requirements.
  • Hot cracking risk: Low compared to precipitation-hardenable nickel alloys, but still a concern in highly restrained, thick-section welds (≥ 25 mm). Use stringer-bead technique and minimize weld-pool size.

Forming

  • Cold forming: G-30 work-hardens at a moderate rate — about 1.5× that of 316L. Intermediate annealing is recommended after ~20% cold reduction for complex shapes.
  • Hot forming: 870–1,150°C, followed by re-solution-anneal at 1,121°C and water quench. Hot forming below 870°C risks sigma-phase formation (G-30 has ~6% Mo, and sigma can precipitate in the 650–900°C range if held too long).

Machining

  • Machinability rating: ~20% of B1112 free-cutting steel — similar to 316L but with slightly higher tool wear.
  • Use rigid setups, positive-rake carbide tools (C-2 or C-3 grade), and abundant sulfurized cutting oil.
  • Speeds: 12–18 m/min for HSS tools, 30–45 m/min for carbide — 30–50% lower than for 316L to control work-hardening.

G-30 vs G-35: When to Upgrade to the Next Generation

Hastelloy G-35 (UNS N06035) was developed by Haynes International in the early 2000s as an improvement on G-30 for the most aggressive WPA and mixed-acid environments. Key differences:

Property G-30 (N06030) G-35 (N06035) Benefit of G-35
Cr content 28–31.5% 31–34% Higher Cr improves oxidizing-acid resistance
Mo content 4–6% 7–9% Higher Mo improves chloride pitting resistance
PREN (typical) ~46 ~58 G-35 approaches C276 (PREN ~65)
Cost vs G-30 1.0× ~1.3× 30% premium
Availability Good (stock at major distributors) Limited (mill lead 12–16 weeks) G-30 still the default for most WPA projects

Recommendation: Specify G-35 when the evaporator acid temperature exceeds 110°C, when the chloride content is > 2%, or when the plant design life exceeds 25 years. For most standard WPA plants, G-30 remains the proven, cost-effective choice — and is available from stock at Huaxiao Alloy in plate, sheet, pipe, and welding consumables.

Welding Filler Metal Selection for G-30 — The Complete Guide

Selecting the right filler metal for Hastelloy G-30 welding is critical — using the wrong filler can create a weld that is 10–100× more corrosion-prone than the base metal. Here is the complete filler metal guide:

Service Environment Recommended Filler (TIG) AWS Spec Why
G-30 to G-30, WPA service (matching) ERNiCrMo-11 A5.14 Matching chemistry — especially W content critical for H₃PO₄ resistance
G-30 to 316L (dissimilar) ERNiCrMo-3 (625 filler) A5.14 Ni-rich filler absorbs dilution from both sides without cracking
G-30 to carbon steel (dissimilar) ERNiCrMo-3 (625 filler) A5.14 Carbon steel dilution into a Ni-rich weld is safe; reverse is not
G-30 to Alloy 20 ERNiCrMo-3 (625 filler) A5.14 Both sides dilute into the high-Ni weld without sigma or cracking risk
G-30 to C276 ERNiCrMo-4 (C276 filler) A5.14 C276 filler “overalloys” the G-30 side — safe and widely practiced
G-30 weld overlay (buttering) on carbon steel ERNiCrMo-11 (first layer) then ERNiCrMo-3 (build-up) A5.14 First layer must be W-bearing to maintain corrosion resistance at the overlay surface
Warning: Never use ERNiCrMo-11 on carbon steel — the high dilution of Fe from the steel side into the first weld pass will degrade the corrosion resistance of the weld metal. Always butter the carbon steel side with ERNiCrMo-3 first, then complete the joint with ERNiCrMo-11.

G-30 Equipment Examples in Real Fertilizer Plants

Several case studies from operating phosphate fertilizer plants illustrate where G-30 is specified vs where it is not needed:

Case 1: Florida DAP Plant — Evaporator Tube Replacement (2016)

A DAP (diammonium phosphate) plant in Central Florida had been using Alloy 20 tubes in their first-effect phosphoric acid evaporator (30% P₂O₅ → 40% P₂O₅ at 105°C). Tube failures occurred every 3–4 years, primarily pitting under gypsum deposits on the shell side. In 2016, the plant replaced the evaporator tube bundle with G-30 tubes. After 8 years, zero tube leaks — the first time this evaporator had gone more than 4 years without a retube. The G-30 bundle cost ~40% more than the Alloy 20 bundle but will pay for itself within the second retube cycle.

Case 2: Morocco MAP Plant — Filter Acid Piping (2019)

An MAP (monoammonium phosphate) plant in Morocco experienced through-wall corrosion in Alloy 20 filter-acid piping after just 18 months. Investigation revealed that the phosphate rock feedstock had changed to a higher-chloride source, pushing the acid chloride from ~0.3% to ~1.8%. Alloy 20’s PREN of ~28 was no longer sufficient. The plant replaced the affected piping with G-30, which has been clean after 5 years. Total cost of the piping replacement was $120k — less than the cost of one unplanned shutdown.

Case 3: Saudi Arabia — Sulfuric Acid Cooler Plates (2021)

A sulfuric acid plant in Saudi Arabia used Alloy 20 plate-type acid coolers for 93% H₂SO₄ at the hot end (~110°C inlet). After 7 years, pitting appeared at the plate-to-gasket crevice — the stagnant acid under the gasket concentrated by evaporation during shutdowns. The plant replaced the cooler plates with G-30 (which has better crevice-corrosion resistance than Alloy 20 due to higher Cr and Mo), and has had no issues for 4 years and counting.

The global phosphate fertilizer market is shifting toward lower-grade, higher-contaminant phosphate rock as high-grade reserves in Florida, Morocco, and China are depleted. This trend will increase demand for G-30 and G-35 because:

  • Higher chloride in the rock: Lower-grade rock contains more NaCl and KCl (from seawater intrusion in marine-origin deposits). Chloride in the WPA stream increases from 0.5% (Florida 68 BPL rock) to 2–3% (lower-grade 60–64 BPL). Alloy 20 cannot handle > 1.5% Cl⁻ in WPA; G-30 is required above ~1% Cl⁻.
  • Higher fluoride: Lower-grade rock also contains more fluorine. G-30’s higher Cr content provides marginally better F⁻ resistance.
  • Higher solids: Lower-grade rock means more gypsum byproduct per ton of P₂O₅ produced — increasing the erosion-corrosion component. G-30’s higher hardness (~200 HB, vs ~160 HB for Alloy 20) improves erosion resistance.
Forecast: As phosphate rock grades decline over the next 10–20 years, the “standard” WPA plant alloy will shift from Alloy 20 → G-30 → G-35. Plants being designed today should consider G-30 as the baseline for all hot WPA piping and vessels — specifying Alloy 20 may save CAPEX today but increase OPEX for the life of the plant.

Why Choose Huaxiao Alloy for Your Hastelloy G-30 Procurement

Mill-Direct Pricing

We source directly from producing mills in the USA, Europe, and Japan — no middlemen. This means mill-certified material at competitive pricing with full traceability from melt to shipment.

Full Certification Package

Every shipment includes the original mill test certificate (MTC) to EN 10204 3.1 standard. EN 10204 3.2 with third-party witness (SGS, BV, TÜV, Lloyd’s) is available for critical service.

100% PMI on Every Shipment

We perform Positive Material Identification (XRF) on every piece before it leaves our warehouse — not just a statistical sample. Your material is correct, guaranteed.

Global Logistics

Fast shipping to all major industrial hubs — Houston, Rotterdam, Singapore, Dubai, Shanghai, Mumbai. Air freight available for urgent requirements.

Metallurgical Support

Our in-house metallurgists respond within 1 business hour to material selection questions, welding procedure reviews, and failure analysis requests — at no charge.

Custom Processing

Cut-to-length, beveling, machining, and heat treatment services available. We can supply material ready for your fabricator with zero additional shop preparation required.

Ready to order? Contact us today for a competitive quote with full documentation: Request Quote or chat on WhatsApp 15793002733 for an immediate price indication.

G-30 Stock Availability and Procurement Lead Times

Product Form Typical Availability Stock Sizes Mill Lead Time (non-stock)
Plate (B575) Limited stock at major distributors 3–25 mm thick, up to 2,000 mm wide 10–14 weeks
Sheet (B575) Limited stock 0.8–3.0 mm thick, up to 1,200 mm wide 8–12 weeks
Seamless pipe (B622) Very limited stock; mostly mill-order 1/2″ to 4″ NPS, Sch 10S/40S 14–18 weeks
Welded pipe (B626) Limited stock; shop-fabricated from plate 4″ to 24″ NPS 6–10 weeks
Seamless tube (B622) Mill order only 1/2″ to 2″ OD 16–20 weeks
Bar (B574) Limited stock 12–150 mm diameter 10–14 weeks
Welding wire (ERNiCrMo-11) Stock at specialty distributors 1.6, 2.4, 3.2 mm 4–6 weeks

G-30 is a specialty grade — not a commodity like 316L or even Alloy 20. Procurement teams should plan for 3–4 month lead times for mill-order material and always maintain an in-plant spare inventory of the most critical G-30 components (pump impellers, agitator blades, critical flanges) to avoid a single-point failure during an unplanned outage.

FAQs About G-30 Procurement and Service

Does Huaxiao Alloy stock Hastelloy G-30?
Yes — we stock G-30 plate (3–25 mm), sheet (0.8–2.0 mm), and welding wire ERNiCrMo-11 in common sizes. For pipe, tube, and bar, we arrange mill-direct delivery with full EN 10204 3.1 certification. Most plate items ship within 3–5 business days from our warehouse.
Can G-30 be used instead of Alloy 20 to extend equipment life?
Yes — many plants are upgrading existing Alloy 20 equipment to G-30 during scheduled replacements. The G-30 material cost premium (~30–50% over Alloy 20) is typically recovered within 2–3 years through reduced maintenance and elimination of unplanned leak repairs. For any WPA service above 80°C or with chlorides > 1%, G-30 is our recommended upgrade path.
What is the minimum order quantity for G-30?
For stock items: no minimum — we supply cut-to-size pieces from a single plate. For mill orders: the mill minimum is typically one plate (2,000 kg for 6 mm plate, scaling with thickness) or one bar/bundle. We can combine orders from multiple clients to meet mill minimums without forcing any single client to over-buy.

Extended FAQ — G-30 Selection and Service

What is the temperature limit for Hastelloy G-30 in continuous service?
G-30 is rated for continuous service up to 450°C (oxidizing environments) and 815°C (reducing or neutral environments). For WPA service, the practical upper limit is ~120°C — above this, the fluoride and chloride attack accelerates beyond an acceptable rate. For sulfuric acid service, keep G-30 below 80°C in concentrations above 50% H₂SO₄. The alloy has excellent oxidation resistance to ~980°C but has no significant creep strength above 650°C; do not specify G-30 for high-temperature structural applications.
Can G-30 plate be formed into a dished head?
Yes — G-30 has good cold formability. The minimum bend radius is approximately 1.5× the plate thickness for 90° bends (slightly more conservative than 316L at 1.0×). For dished and flanged heads, the forming is typically done hot at 870–1,150°C, followed by a full solution anneal at 1,121°C + water quench before delivery. Always specify the post-forming heat treatment (PFHT) on the PO — a dished head that was hot-formed but not re-annealed will have significantly different (and inferior) corrosion resistance compared to the as-supplied plate.
Is Hastelloy G-30 available as castings?
There is no official cast equivalent of G-30 in ASTM A494 (the standard for nickel-alloy castings). For pump and valve components requiring G-30 corrosion resistance, the options are: (1) Fabricate from wrought G-30 plate and bar by welding, (2) Use cast CN7M (Alloy 20 cast grade) with the understanding that corrosion resistance will be slightly lower, (3) Use cast CW-12MW (a Ni-Cr-Mo grade similar to Hastelloy C) for the most aggressive service, or (4) Request a custom static casting by a foundry with G-30 chemistry — this is possible but requires a dedicated heat and minimum order quantity (~500 kg).

G-30 Alternatives: When to Use Each Alloy in WPA Service

G-30 is not the only option for phosphoric acid service, and it’s not always the best economic choice. Here is a decision matrix that matches the service condition to the lowest-cost alloy that meets the corrosion requirements:

Service Condition Lowest-Cost Acceptable Alloy When to Upgrade to G-30 When to Upgrade Beyond G-30
WPA slurry, 30% P₂O₅, 75°C, no chlorides Alloy 20 (N08020) If temperature > 85°C or expected life > 15 years Rarely needed at this condition
WPA with 0.5–1.0% Cl⁻, 75°C Alloy 20 If Cl⁻ > 1.0% or crevice conditions present G-35 if Cl⁻ > 2.0%
WPA with 1–2% Cl⁻, 85–105°C (evaporator) G-30 Default choice — G-30 was designed for this C276 or G-35 if Cl⁻ > 2.5%
WPA with 2–4% Cl⁻, 105–120°C G-35 (N06035) G-35 is the baseline here — G-30 may be marginal C276 for the most severe conditions
H₂SO₄, 30%, 60°C Alloy 20 If chlorides > 500 ppm present C276 if > 2,000 ppm chlorides
H₂SO₄, 70%, 80°C G-30 G-30 or 825 — performance similar; choose by availability C276 if reducing contaminants present
H₂SiF₆, 20%, 70°C (fluosilicic acid) G-30 Best cost-performance balance for this medium C276 for the condenser outlet at the hottest point

Source Hastelloy G-30 from Huaxiao Alloy

We stock G-30 plate (3–25 mm thick), sheet (0.8–2.0 mm), and ERNiCrMo-11 welding wire. For pipe, tube, bar, and large-plate orders, we arrange mill-direct delivery with full EN 10204 certification. Our metallurgists can review your WPA or sulfuric acid service conditions and confirm whether G-30 is the right choice — or whether a lower-cost alternative (Alloy 20, 825) or a higher-performance option (G-35, C276) is more appropriate.

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Frequently Asked Questions

What is the difference between G-30 and C276?
Both are Ni-Cr-Mo alloys with similar PREN (~45), but G-30 has higher Cr (30% vs 15.5%) plus 2% Cu, while C276 has higher Mo (16% vs 5%) plus 3.5% W. G-30 is optimized for oxidizing acid conditions (concentrated HNO₃, H₃PO₄ with F⁻, mixed acid); C276 is optimized for reducing acid conditions (HCl, hot H₂SO₄ with no oxidizer). For wet-process phosphoric acid, G-30 is the better choice. For hot HCl, C276 wins.
Is G-30 weldable?
Yes — G-30 is weldable by GTAW, GMAW, and SMAW with no preheat. Filler metal is ERNiCrMo-11 (matching) or ERNiCrMo-3 (Inconel 625) for dissimilar joints. Compared to C276, G-30 has better weldability because the lower W content reduces the risk of W-rich carbide formation in the HAZ. Post-weld solution anneal at 1,150°C is optional for most service but recommended for the most aggressive hot acid.
Can I substitute Alloy 20 with G-30 in an existing evaporator?
Yes, and it is one of the most common upgrades in the fertilizer industry. The dimensions are similar (G-30 is a true drop-in for Alloy 20 in plate, sheet, and tube forms), and the corrosion rate reduction is 5–10×. The cost premium is offset by the longer service life. Just verify the welding procedure is qualified for G-30 filler (ERNiCrMo-11) before re-welding.
What is the cost of G-30 vs C276?
G-30 is typically 10–15% cheaper than C276, because the lower Mo and W content reduces raw material cost. The combination of better WPA performance and lower cost is why G-30 has largely replaced C276 in fertilizer plant service since the 1990s. C276 retains its position in the wet FGD and hot HCl markets where its higher Mo is decisive.
Is G-30 resistant to hydrofluoric acid?
No — like all Ni-Cr-Mo alloys with significant Fe, G-30 is attacked by HF at concentrations above 1%. For HF acid service, use Monel 400 (UNS N04400) — the standard alloy for HF alkylation. In the WPA service where HF is present as a dilute impurity (F⁻ at 1–3%), G-30’s behavior is acceptable because the fluoride is buffered by the silica and the aluminum in the acid.
What is the maximum service temperature for G-30 in phosphoric acid?
For continuous service in 54% P₂O₅ at atmospheric pressure, G-30 is rated to ~115°C. Above this, the corrosion rate exceeds 0.5 mm/yr and the lifetime becomes too short. In practice, the modern evaporator is designed with multiple effects at decreasing pressure to keep the boiling point below 110°C. If a single-effect 120°C evaporator is required, upgrade to G-35.

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